Van't Hoff's Factor

IMPORTANT

Van't Hoff's Factor: Overview

This Topic covers sub-topics such as Abnormal Molar Mass, Van't Hoff's Factor, Abnormal Colligative Properties and, Relation between Observed, Calculated Colligative Properties and Van't Hoff's Factor

Important Questions on Van't Hoff's Factor

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Select the correct statements:

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Acetic acid undergoes dimerisation in benzene, the van't Hoff factor i is related to degree of association of acid α, as

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Which of the following aqueous solutions have higher freezing point?

HARD
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If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the observed freezing point will be _____ % higher than the expected/theoretical freezing point. (Nearest integer).

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The degree of dissociation of monobasic acid is 0.3, By what percent is the observed depression in freezing point greater than the calculated depression in freezing point?

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How many of the following have same Relative lowering vapour pressure?

(A) 1M NaCl 

(B) 1.5 M AlCl3

(C) 1M urea

(D) 2M Na2SO4

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Which has highest freezing point :

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Vant hoff factor is dependent or independent of Concentration?

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The Van't Hoff's factori for a 0.2 molal aqueous solution of urea is _____

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72.5 g of phenol dissolved in 1kg solvent kf=14. If depression in freezing point is 7K. Find the %phenol that dimerised.

Round off your answer to the nearest integer.

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The freezing point of 0.2 M HA acid is -0.558°C. The dissociation constant of acid is

Given: kf=1.86 °C/m

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What is degree of association ?

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A quantity of 1.04 g of CoCl3.6NH3Molecular weight=267 was dissolved in 100 g of H2O. The freezing point of the solution was -0.29C. How many moles of solute particle exist in the solution for each mole of solute introduced? Kf for water =1.86C m-1

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Van't Hoff factor in case of 50% dissociation of PCl5 is :

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0.01 molal solution of ammonia freezes at -0.02C. Calculate the Van'tHoff factor, i and the percentage dissociation of ammonia in water. 

KfH2O=1.86 deg molal-1

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The osmotic pressure of 0.5M aqueous solution of CH3COOH having pH = 2 at temperature T is _____

EASY
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Out of the following three solutions, which has the highest freezing point and why ? (i) 0.1 M Urea (ii) 0.1 M Barium phosphate (iii) 0.1 M Sodium sulphate

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 Out of the following three solutions, which has the Lowest boiling point and why ? (i) 1 M Glucose (ii) 1 M Potassium chloride (iii) 1 M Aluminium nitrate

EASY
IMPORTANT

Out of the following three solutions, which has the lowest freezing point and why ? (i) 0.1 M Urea (ii) 0.1 M Barium phosphate (iii) 0.1 M Sodium sulphate

MEDIUM
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 Out of the following three solutions, which has the Lowest boiling point and why ? (i) 1 M Glucose (ii) 1 M Potassium chloride (iii) 1 M Aluminium nitrate